Product ID:00365 TEXACO UNLEADED GASOLINE
MSDS Date:06/07/1991
FSC:9130
NIIN:00-264-4539
MSDS Number: BNKPT

TEXACO REFINING AND MARKETING, INC.

HOUSTON, TX 77052
US

Emergency Phone: 914-831-3400

Info Phone: 914-838-7204

Cage: 2R503

TEXACO REFINING AND MARKETING INC

HOUSTON, TX 77002-3310 US

Telephone: 713-650-5206

Cage: 2R503

BENZENE (SARA III)

CAS: 71-43-2

RTECS: CY1400000

Fraction By Weight: 1-3.99%

OSHA PEL 1PPM/5STEL;1910.1028

ACGIH TLV: 10 PPM; A2; 9192

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 4-10.99%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

ETHYL BENZENE (SARA III)

CAS: 100-41-4

RTECS: DA0700000

Fraction By Weight: 1-3.99%

OSHA PEL 100 PPM/125 STEL

ACGIH TLV: 100 PPM/125STEL 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 4-10.99%

OSHA PEL 100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,2,4-TRIMETHYLBENZENE (SARA III)

CAS: 95-63-6

RTECS: DC3325000

Fraction By Weight: 1-3.99%

OSHA PEL 25 PPM

ACGIH TLV: 25 PPM; 9192

METHYL TERT-BUTYL ETHER (SARA III)

CAS: 1634-04-4

RTECS: KN5250000

Fraction By Weight: 0-15%

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

GASOLINE

CAS: 8006-61-9

RTECS: LX3300000

Fraction By Weight: BALANCE

OSHA PEL 300 PPM/500 STEL

ACGIH TLV: 300 PPM/500STEL;9192

LD50 LC50 Mixture:ORAL LD50 (RAT) BELIEVED > 5 G/KG
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:EYE IRRITATION, PROLONGED OR
WIDESPREAD SKIN CONTACT MAY RESULT IN ABSORPTION OF POTENTIALLY
HARMFUL AMOUNTS, BRIEF CONTACT MAY CAUSE SKIN IRRITATION,
RESPIRATORY TRACT IRRITATION, CENTRAL NERVOUS SYS TEM DISTURBANCES,
ASPHYXIATION HAZARD, GASTROINTESTINAL DISTURBANCES, ASPIRATION
HAZARD.
Explanation of Carcinogenicity:PRODUCT CONTAINS BENZENE WHICH IS LISTED
AS A CARCINOGEN BY NTP, IARC AND OSHA.
Effects of Overexposure:EYE DISCOMFORT/REDNESS, SKIN REDNESS/SWELLING,
NOSE/THROAT IRRITATION, HEADACHE, NAUSEA, VOMITING, DIZZINESS,
DROWSINESS, EUPHORIA, LOSS OF COORDINATION, DISORIENTATION,
UNCONSCIOUSNESS, ABDOMINAL DIS COMFORT, DIARRHEA.
Medical Cond Aggravated by Exposure:BECAUSE OF ITS IRRITATING
PROPERTIES, REPEATED SKIN CONTACT MAY AGGRAVATE AN EXISTING
DERMATITIS.

First Aid:EYES: IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES, HOLDING
EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN: WASH WITH SOAP AND
WATER. REMOVE CONTAMINATED CLOTHING. INGESTION: DO NOT INDUCE
VOMITING. GET MED ICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO
AN UNCONSCIOUS VICTIM. INHALATION: REMOVE TO FRESH AIR. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT,
GIVE OXYGEN. CALL MD.

Flash Point Method:COC
Flash Point:=-40.C, -40.F
Lower Limits:1.4 %
Upper Limits:7.6 %
Extinguishing Media:DRY CHEMICAL, FOAM, CARBON DIOXIDE.
Fire Fighting Procedures:WATER MAY BE INEFFECTIVE ON FLAMES, BUT SHOULD
BE USED TO COOL FIRE-EXPOSED CONTAINERS. IF A SPILL OR LEAK HAS NOT
IGNITED, USE WATER SPRAY TO DISPERSE VAPORS.
Unusual Fire/Explosion Hazard:GASOLINE VAPORS ARE HEAVIER THAN AIR AND
MAY TRAVEL A CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND
FLASH BACK. FLOWING GASOLINE CAN GENERATE ELECTRICITY.

Spill Release Procedures:ELIMINATE ALL IGNITION SOURCES INCLUDING
INTERNAL COMBUSTION ENGINES AND POWER TOOLS. VENTILATE AREA. STAY
UPWIND. CONTAIN SPILL IF POSSIBLE. REMOVE WITH INERT ABSORBENT.
PREVENT ENTRY INTO SEWERS AND WATERWAYS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARKS, FLAMES
AND OTHER SOURCES OF IGNITION. MATERIAL MAY BE AT ELEVATED
TEMPERATURES AND/OR PRESSURES.
Other Precautions:EXERCISE DUE CARE WHEN OPENING BLEEDERS AND SAMPLING
PORTS. WHEN HANDLING, USE NON-SPARKING TOOLS, GROUND AND BOND ALL
CONTAINERS. CONSULT NFPA 77 FOR THE PROPER HANDLING PRECAUTIONS.

Respiratory Protection:IF VAPOR, MIST OR DUST IS GENERATED, USE
RESPIRATOR APPROVED BY MSHA OR NIOSH AS APPROPRIATE. SUPPLIED AIR
RESPIRATORY PROTECTION SHOULD BE USED FOR CLEANING LARGE SPILLS OR
UPON ENTRY INTO TANKS, VES SELS OR OTHER CONFINED SPACES.
Ventilation:ADEQUATE TOMEET RECOMMENDED OCCUPATIONAL EXPOSURE LIMITS.
Protective Gloves:NITRILE, TEFLON, VITON
Eye Protection:CHEMICAL-TYPE GOGGLES, FACE SHIELD
Other Protective Equipment:UNIFORMS, COVERALLS, BOOTS SHOULD BE WORN
WHERE CONTACT WITH PRODUCT IS LIKELY.
Work Hygienic Practices:WASH WITH SOAP AND WATER AFTER HANDLING PRODUCT
AND BEFORE EATING DRINKING OR SMOKING.
Supplemental Safety and Health
LAUNDER OR DRY CLEAN CONTAIMINATED CLOTHING BEFORE REUSE. GROUND AND
BOND SHIPPING CONTAINER, TRANSFER LINE AND RECEIVING CONTAINER.
NOTE TO PHYSICIAN: ASPIRATION OF THIS PRODUCT CAN RESULT IN LUNG I
NJURY. IF EVACUATION OF STOMACH CONTENTSIS CONSIDERED NECESSARY,
USE METHOD LEAST LIKELY TO CAUSE ASPIRATION.

HCC:F1
Boiling Pt:>32.2C, 90.F
Vapor Pres:465-775
Vapor Density:3 - 4.0
Spec Gravity:0.7 - .77
Evaporation Rate & Reference:NOT GIVEN
Solubility in Water:SLIGHT
Appearance and Odor:LIGHT STRAW TO LIGHT RED LIQUID
Percent Volatiles by Volume:100 %

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS
Stability Condition to Avoid:HEAT, SPARKS, FLAME AND OTHER SOURCES OF
IGNITION.
Hazardous Decomposition Products:TOXIC LEVELS OF CARBON MONOXIDE,
CARBON DIOXIDE, IRRITATING ALDEHYDES AND KETONES.

Waste Disposal Methods:PREVENT WASTE FROM CONTAMINATING SURROUNDING
ENVIRONMENT. DISCARD ANY PRODUCT, RESIDUE, DISPOSAL CONTAINER OR
LINER IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.